Ligands and Complexes for Asymmetric Reactions.Product classM-P, Homogeneous Catalysts, M-C, Arene/Aryl Ligands, Phosphorus Ligands - ChiralReaction typeHydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer HydrogenationChemical propertiesChemical formulaC54H46Cl2P2RuEmpirical formula[RuCl(p-cymene)(R)-BINAP]ClMolecular weight928.88MetalRuTheoretical metal content11Physical statepowderColorred orangeApplications & referencesSynthesis of chiral acid derivatives by asymmetrical hydrogenation of the corresponding (E)-allylic ethers in the preparation of spiro-substituted glutaramide derivatives.Reference: EP644176Asymmetric hydrogenation of halogenated acetophenones to enantiomerically pure halogenated phenyl ethanol derivatives.Reference: Cat. Lett. 1996, 41, 111 (DOI: 10.1007/BF00811721)Highly enantioselective catalytic hydrogenation of methyl-N-tertbutyl-3-oxoglutarate as a key step in the total synthesis of rovastatin.Reference: Tetrah. Lett. 2008, 49, 4836 (DOI: 10.1016/j.tetlet.2008.06.018)Enantioselective hydrogenation of 4-(hydroxymethyl)furan-2(5H)-one derivatives.Reference: J. Mol. Cat. A: Chem. 2006, 259, 103 (DOI: 10.1016/j.molcata.2006.05.066)

包装规格	库存	价格	优惠幅度	操作
100mg	现货	¥72.5	9%	72.5元
500mg	现货	¥213.5	11%	213.5元
1g	现货	¥373.5	13%	373.5元
5g	现货	¥1547.0	14%	1547元

氯代[(R)-(+)-2,2′-双(二苯基膦)-1,1′-联萘](p-伞花素)氯化钌(II)

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